It is possible to prevent spiderwebs from overtaking the outside of your house without power-washing or chemical insect repellants. All-natural sprays called "web repellants" use a combination of all-natural essential oils -- like thyme, lemongrass and citronella -- and liquid soap to make these areas of your home less attractive to spiders. The arachnids will avoid where you spray and set up their webs, which are effective to keep insects like mosquitoes at bay, elsewhere.
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